박상우 Sang-woo Park

DOI:10.9786/kswm.2018.35.8.683

Abstract

The plastic strategy adopted by the EU in January 2018 was established to implement circular economic policies and the Sustainable Development Goals(SDGs) of the United Nations. The strategy includes the vision and implementation measures to achieve, which are primarily measures to improve recycling and increase demand for recycled plastics. The representative measures include the design that considers recycling possibilities, reinforcement of demand for recycled plastics, suppression of occurrence, and response to micro-plastics. The policies to implement these measures include legislative restrictions and economic measures (EPR, GPP). It is especially desirable that the policies are applied differently depending on the plastic product. The Korean government has established comprehensive measures for all stages from production to recycling, but those measures are not comprehensive compared to the EU’s strategy. The reason is that the refusal of waste collection makes the Korean government establish the approach from the aspect of waste management instead of the implementation of a circular economy or SDGs like the EU. The countermeasures are aimed at achieving a 50% reduction in waste generation amount and a 70% recycling rate. It is considered that the possibility of achieving the goal will increase by examining the measures and policy means in the EU’s plastics strategy.

Key Words

Sustainable development, Plastics strategy, Waste management

연진모 Jin-mo Yeon , 김우일 Woo-il Kim , 황동건 Dong-gun Hwang , 조나현 Na-hyeon Cho , 김기헌 Ki-heon Kim , 이영기 Young-ki Lee

DOI:10.9786/kswm.2018.35.8.692

Abstract

In this study, the results of PBDEs and HBCDs of the products and waste that contain BFRs such as domestic electronic products, automobiles and textile products were compared with international management standards, and their excess rates were calculated. Deca-BDE was detected among the PBDEs in TV rear cover plastics, car seats, automotive interior plastics, and automobile shredding residues of products and waste containing BFRs. The comparison with Basel Convention management standards (1,000 mg/kg) for PBDE-containing wastes (4 types in total) shows that the excess rate of all samples was less than 1.5%. The estimated excess rate compared to the EU and Basel convention management standards (1,000 mg/kg) for PBDEs (4 species + deca-BDE) and TV rear cover plastics was 37.5% (30 of 80 samples exceeded the standards). The estimated excess rate compared to the Basel convention management standards (1,000 mg/kg) for HBCD, building materials products and waste was 15.7% (17 of 108 samples exceeded the standards). In the case of PBDEs, it is necessary to remove only the rear cover of CRT TV among the electric and electronic products and treat it in the flame retardant treatment facility to improve the recycling collection system. In the case of HBCD, it is necessary to appropriately dispose of the recycled materials, heat insulation materials, TV plastics, and styrofoam in marine fishery among construction materials and restrict the use as recycled raw materials.

Key Words

Brominated flame retardants, Polybrominated biphenyls, Hexabromocyclododecane, Hexabromobiphenyl

양회원 Hoiweon Yang , 안조환 Johwan Ahn , 김장호 Jangho Kim , 김정환 Junghwan Kim

DOI:10.9786/kswm.2018.35.8.701

Abstract

Chemical batch tests were conducted to investigate the amount of nutrients that were released from the wasted activated sludge during microwave heating. For this study, three types of activated sludge were obtained from A₂/O, MLE and oxidation ditch (OD) processes. Polyphosphate-accumulating organisms in the activated sludge have a unique trait: they releases phosphate from the cell when they are exposed to high temperatures. The sludge obtained from the A₂/O process released the largest amount of phosphate, followed by those from the MLE and OD processes. The release of phosphate increased with increasing polyphosphate content in the sludge under strongly alkaline or acidic conditions. Furthermore, ammonia and heavy metals were released with phosphorous. The largest amount of ammonia was observed from the sludge obtained from the MLE process. The release of heavy metals strongly depends on the pH conditions. Therefore, the chemical analysis results strongly suggest that both phosphorus and ammonia react with Mg²⁺ or Ca²⁺ to form metal complexes such as magnesium ammonium phosphate or hydroxyapatite under alkaline conditions.

Key Words

Ammonia, Heavy metal, Microwave heating, Polyphosphate-accumulating organisms, Phosphorus, Wasted activated sludge

최형진 Hyeong-jin Choi , 최용 Yong Choi , 이승희 Seung-whee Rhee

DOI:10.9786/kswm.2018.35.8.709

Abstract

Since the import ban of plastic waste in China has been enforced, plastic wastes were not properly collected and recycled in Korea. Hence, the management strategies for plastic waste in Korea should be improved by examining the regulations and policy in developed countries such as United States, Japan, EU and United Kingdom. The management strategy for the recycling cycle should be implemented to expand the labeling system of separation and discharge, reduce the consumption of plastic products, automate the separation and sorting method in recycling facilities, and improve the economical efficiency of the recycling cycle. The concept of residual waste (secondary waste) in the material flow analysis should be implemented to identify the shortage point in the plastic waste stream. Finally, the cooperation with international communities is required for a transboundary movement of plastic waste, which includes participation at the working group of international standards to recycle plastic waste.

Key Words

Plastic waste, Resources circulation, Waste management, Management strategy

김용준 Yong-jun Kim , 엄남일 Nam-il Um , 김우일 Woo-il Kim , 이영기 Young-kee Lee , 김기헌 Ki-heon Kim

DOI:10.9786/kswm.2018.35.8.721

Abstract

We investigated the effects of heavy metals in cement in the last 3 years and the amount of waste in the cement manufacturing process. The result shows that the average Cr⁶⁺ content in cement products is controlled at 10 mg/kg. Cu and Pb have lower detection tendency in white cement than in ordinary portland cement. In addition, heavy metals such as Cd show a certain level of detection regardless of the input wastes. Copper slag and phosphate gypsum are the main influencing factors on the heavy metals in cement products. In auxiliary fuels, plastics waste and wood waste are considered to affect heavy metals in cement products. Alternative raw materials are considered to be affected by the alternative raw materials managed as byproducts. In the case of supplementary fuels, auxiliary fuels managed as waste instead of auxiliary fuels managed as byproducts affect the heavy metals in cement. This study examined the input amount without considering the heavy metals in each waste. Therefore, the result may vary in different situations, and further research must be conducted to supplement the findings. However, if the heavy-metal contents in the waste are constant, it can be used as a reference material for the control of heavy metals in cement products.

Key Words

Portland cement, Heavy metals, Correlation

한소영 So-young Han , 강호 Ho-kang , 최연석 Yeon-seok Choi , 김치열 Chi-yeol Kim

DOI:10.9786/kswm.2018.35.8.731

Abstract

This study was performed to test the feasibility of thermophilic (55oC) co-digestion of municipal sewage sludge and food wastes. The management variables of co-digestion were the mixed ratios of municipal sewage sludge and food waste hydraulic retention times (HRTs). During the operation of thermophilic co-digestion, the reactor pH ranged from 7.0 to 7.5 and the reactor alkalinity remained above 3,200 to 4,000 mg/L as CaCO₃. The volatile fatty acids concentration increased as the HRT shortened from 20 days to 10 days and the mixture ratio increased to 1:4, but did not reach toxic levels for co-digestion of sewage sludge and food wastes. Methane productivity increased gradually as the organic loading rate increased. Maximum methane productivity reached 1.03v/v-d at an HRT of 10 days and at the mixture ratio of 1:4. The TVS removal efficiency decreased from 70.6% to 58.3% as the HRT shortened from 20 days to 10 days. TVS removal efficiency ranged from 57.0% to 77% during the entire operation. It is likely that thermophilic co-digestion of sewage sludge and food wastes is a very effective method both to environmentally treat food waste and to economically produce gas for energy.

Key Words

Food waste, Municipal sludge, Thermophilic co-digestion

권은혜 Eun-hye Kwon , 윤영삼 Young-sam Yoon , 배지수 Ji-su Bea , 전태완 Tae-wan Jeon , 이영기 Young-ki Lee

DOI:10.9786/kswm.2018.35.8.744

Abstract

The Stockholm Convention, which was adopted in Sweden in 2001 to protect human health and the environment, includes regulations for Persistent Organic Pollutant Rotors such as toxic and bioaccumulatives. Currently, there are 28 types of materials. This prohibits and limits the production, use, and manufacture of products. Korea is a member of the Convention, and it is necessary to prepare management and treatment plans to address the POP trends. Thus, we experimentally investigate whether the environmentally stable incineration is achieved when the sample is thermally treated using the Lab-scale (1 kg/hr). The target samples is pesticides in liquid phase and solid phase. In this study, organic chlorinated pesticides and their thermal characteristics were analyzed. We calculated the theoretical air volume based on the element analysis results. Because the interior of the reactor is small, more than 10 times of the air ratio was injected. The retention time was set to at least 4 seconds using a margin. The incineration temperature was 850oC and 1100oC. Thus, we experimentally investigated whether the environmentally stable incineration was achieved when the sample was thermally treated using the Lab-scale (1 kg/hr). We analyzed five types of exhaust gas; the 02 concentration was high, but the CO amount decreased. Complete combustion is difficult because of the small size of the furnace due to the nature of Lab-scale. The organic chlorine-containing pesticide had an average decomposition rate of 99.9935%. Considering the decomposition rates of organic chlorine-containing pesticide in this study, the incineration treatment at over 2 ton/hour, which is typical for a conventional incinerator, is possible. Considering the occurrence of dioxins and unintentional persistent organic pollutants, it can operate at more than 1,100oC.

Key Words

Thermal treatment, Organochlorine pesticide, Reactor

이창열 Chang-yeol Lee , 정복화 Bok-hoa Jeong , 정진도 Jin-do Chung

DOI:10.9786/kswm.2018.35.8.754

Abstract

There is growing concern over the effects of global warning. In response, the power generation sector must consider a wider range of systems and fuels to generate power. One of the classes of solid fuels that is being increasingly developed is biomass. However, one of the most serious problems that biomass plants face is severe corrosion. To mitigate the problem, various approaches have been proposed in terms of additive utilization. This study is based on the results obtained during the co-combustion of wood chip and waste wood in a circulating fluidized bed boiler (CFBC boiler). The KCl concentration was reduced from 59.9 ppm to 3.9 ppm during the injection of ammonium sulfate, and NOx was reduced by 25.5 ppm from 30.6 ppm to 5.1 ppm. However, SOx increased by 110.2 ppm from 33.2 ppm to 143.4 ppm, and HCl increased by 71.5 ppm from 340.5 ppm to 412.0 ppm. Thus, we confirmed that the attitude of the superheater tube was reduced by 87 ~ 93%, and the injection of ammonium sulfate was effective in preventing high-temperature corrosion.

Key Words

Ammonium sulfate, CFBC Boiler, Pollutants, High temperature corrosion, Superheater tube

박상진 Sang-jin Park , 배재근 Chae-gun Phae

DOI:10.9786/kswm.2018.35.8.762

Abstract

This study was carried out to examine the improvement plan by analyzing the characteristics of imported wastes, operation rate, and benefits of energy recovery for incineration facilities with a treatment capacity greater than 50 ton/ day. The incineration facility capacity increased by 3,280 tons over 15 years, and the actual incineration rate increased to 2,783 ton/day. The operation rate dropped to 76% in 2010 and then rose again to 81% in 2016. The actual calorific value compared to the design calorific value increased by 33.8% from 94.6% in 2002 to 128.4% in 2016. The recovery efficiency decreased by 29% over 16 years from 110.7% to 81.7% in 2002. Recovery and sales of thermal energy from the incinerator (capacity 200 ton/day) dominated the operation cost, and operating income was generated by energy sales (such as power generation and steam). The treatment capacity increased by 11% to 18% after the recalculation of the incineration capacity and has remained consistently above 90% in most facilities to date. In order to solve the problem of high calorific value waste, wastewater, leachate, and clean water should be mixed and incinerated, and heat recovery should be performed through a water-cooled grate and water cooling wall installation. Twenty-five of the 38 incineration facilities (about 70%) are due for a major repair. After the main repair of the facility, the operation rate is expected to increase and the operating cost is expected to decline due to energy recovery. Inspection and repair should be carried out in a timely manner to increase incineration and heat energy recovery efficiencies.

Key Words

Municipal Solid Waste (MSW), Incineration facility, Calorific value, Heat energy recovery efficiency, Repair of incineration

권영현 Young-hyun Kwon , 강준구 Jun-gu Kang , 고영재 Young-jae Ko , 유하녕 Ha-nyoung Yoo , 권준화 Jun-hwa Kwon , 박호연 Ho-yeun Park , 전태완 Tae-wan Jeon , 이영기 Young-ki Lee

DOI:10.9786/kswm.2018.35.8.770

Abstract

This study measured the energy recovery rate of each municipal waste incineration facility according to the revised energy recovery rate estimation method, which targeted four municipal waste incineration facilities (Unit No. 7). The results calculated by the measuring instruments were used for each factor to estimate the recovery rate, and the available potential of available energy was examined by analyzing the energy production and valid consumption. As a result of the low heating value, 2,540 kcal/kg was calculated on average when the LHVw formula was applied, which is approximately 116 kcal/kg higher than the average design standard of 2,424 kcal/kg. The energy recovery rate was calculated as 96.9% on average based on production and 67.5% based on effective consumption, and the analysis shows that approximately 29.4% energy can be used.

Key Words

Incineration heat, Incineration facility, Energy recovery, Lower heating value

박만호 Man Ho Park , 김호남 Honam Kim , 주문솔 Munsol Ju , 김희종 Hee Jong Kim , 김재영 Jae Young Kim

DOI:10.9786/kswm.2018.35.8.777

Abstract

Since climate change increases the risk of extreme rainfall events, concerns on flood management have also increased. In order to rapidly recover from flood damages and prevent secondary damages, fast collection and treatment of flood debris are necessary. Therefore, a quick and precise estimation of flood debris generation is a crucial procedure in disaster management. Despite the importance of debris estimation, methodologies have not been well established. Given the intrinsic heterogeneity of flood debris from local conditions, a regional-scale model can increase the accuracy of the estimation. The objectives of this study are 1) to identify significant damage variables to predict the flood debris generation, 2) to ascertain the difference in the coefficients, and 3) to evaluate the accuracy of the debris estimation model. The scope of this work is flood events in Ulsan city region during 2008-2016. According to the correlation test and multicollinearity test, the number of damaged buildings, area of damaged cropland, and length of damaged roads were derived as significant parameters. Key parameters seems to be strongly dependent on regional conditions and not only selected parameters but also coefficients in this study were different from those in previous studies. The debris estimation in this study has better accuracy than previous models in nationwide scale. It can be said that the development of a regional-scale flood debris estimation model will enhance the accuracy of the prediction.

Key Words

Disaster annual report, Flood debris estimation model, Flood damage, Flood management, Multi-linear regression

오길종 Gil-jong Oh , 조윤아 Yoon-a Cho , 김지연 Ji-yeon Kim , 김기헌 Ki-heon Kim

DOI:10.9786/kswm.2018.35.8.785

Abstract

Since the Framework Act on Resource Circulation was enacted in 2018, the government should establish a National Resource Circulation Master Plan every 10 years, which defines mid- to long-term policy goals and directions on the efficient use of resources, prevention of waste generation and recycling of waste. In addition, we must set mid- to longterm and stepwise targets for the final disposal rate, recycling rate (based on sorted recyclable materials and recycled products), and energy recovery rate of wastes, and relevant measures should be taken to achieve these targets. However, the current industrial waste (IW) statistics have limitations in setting these targets because the final disposal rate and recycling rate are calculated as the ratio of the recycling facility input to the IW generation. In this study, the material flow from the collection stage to the final disposal of industrial waste was analyzed based on the generation of 2016, and the actual recycling amount, actual incineration amount, final disposal amount and their rates were calculated. The effect on the recycling, incineration and final disposal rates was examined by changing the treatment method of nonhazardous wastes from the factory and construction and demolition wastes, which were put in landfills in 2016. In addition, the variation of the waste treatment charge was investigated according to the change of treatment methods. The results of this study are expected to be effectively used to establish the National Resource Circulation Master Plan and industrial waste management policy in the future in South Korea.

Key Words

Industrial waste, MFA, Actual recycle rate, Actual landfill rate, Waste treatment charge